Assistant manager Agnew was handed the reins after Aitor Karanka was sacked by Middlesbrough on Thursday following a 10-game winless league run that saw the club slide down the table to 19th, three points from safety.
Meanwhile for Jose Mourinho's visitors, summer signing Henrikh Mkhitaryan has become an integral player under the "Special One" after initially struggling to adapt in English football following his move from Borussia Dortmund.
And Ravanelli has revealed how he wants to return to his former side to save them from Premier League relegation.
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Middlesbrough chairman Steve Gibson could turn to a proven firefighter as he plots the way forward after the departure of head coach Aitor Karanka.
"I think he deserves to be sacked", he said, speaking ahead of United's trip to the Riverside on Sunday.
It is understood that Karanka, with whom Mourinho is still close, clashed with a number of Middlesbrough players, including Stewart Downing and Patrick Bamford.
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"So I think in the fourth year, he deserved to be sacked!"
'In the first year he arrived, the team was going into League One and he saved the team. In the second year, he took the team to Wembley to play the play-off final.
Slaven feels Agnew, who has been caretaker boss in previous years, will not get the role until the end of the season and he is backing Martin O'Neill for the job. "There's more to him than people know and a bit more steel", he said.
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The club have also appointed former Portsmouth, Tottenham Hotspur and QPR coach Joe Jordan to support Agnew during the run-in, with the interim boss expecting Jordan to have a "big impact" on his players.